Internal energy and the first law of thermodynamics

Physics · Heat and thermodynamics. The idea in plain words, the rules to remember, the mistake to avoid and a worked example, written and checked by Mega Lecture.

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The idea

Internal energy U is the sum of all the energies of the molecules of a system. For an ideal gas it is only the kinetic energy of the molecules, so it depends on temperature alone. It is a function of state: the change ΔU does not depend on the path taken.

The first law of thermodynamics is the conservation of energy for heat and work. Heat Q supplied to a system goes partly into raising its internal energy and partly into work W done by the system on its surroundings.

In an isothermal process the temperature stays constant. In an adiabatic process no heat enters or leaves, which happens when a change is very fast or the system is well insulated.

Rules to remember

Common mistake

Getting the sign of W wrong. In Q = ΔU + W, work done on the gas is negative W. If 150 J of work is done on a gas, put W = −150 J, not +150 J.

Worked example

A gas at a constant pressure of 1.5 × 105 Pa expands from 2.0 × 10−3 m3 to 5.0 × 10−3 m3 while 700 J of heat is supplied. Find the change in its internal energy.

  1. ΔV = 5.0 × 10−3 − 2.0 × 10−3 = 3.0 × 10−3 m3.
  2. W = PΔV = 1.5 × 105 × 3.0 × 10−3 = 450 J, done by the gas.
  3. ΔU = Q − W = 700 − 450 = 250 J.

Answer: ΔU = +250 J.

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