Calculating and measuring rates of reaction

Chemistry · The rate and extent of chemical change. The idea in plain words, the rules to remember, the mistake to avoid and a worked example, written and checked by Mega Lecture.

Test this topic freeAll Chemistry topics

The idea

The rate of reaction tells you how fast a reactant is used up or a product is formed. To measure it you need a quantity that changes and the time it takes to change. You can measure the volume of gas collected in a gas syringe, the loss of mass as a gas escapes from a flask on a balance, or the time for a cross under the flask to disappear as the mixture goes cloudy.

On a graph of amount of product against time, the slope shows the rate. A steep line means a fast reaction. The curve becomes less steep as the reactants are used up and is flat when the reaction has stopped. The slope of a tangent gives the rate at one moment.

Rules to remember

Common mistake

Students divide time by quantity, or leave the time in minutes when the answer is wanted per second. Put the quantity on top, the time underneath, and change minutes to seconds first.

Worked example

On a graph of volume of gas against time, the tangent to the curve at 30 s passes through the points (10 s, 20 cm3) and (50 s, 44 cm3). What is the rate of reaction at 30 s?

  1. Change in volume = 44 − 20 = 24 cm3.
  2. Change in time = 50 − 10 = 40 s.
  3. Rate = gradient = 24 ÷ 40 = 0.60 cm3/s.

Answer: 0.60 cm3/s

Ask about this

Type what you are stuck on. The helper finds the explanation, worked examples and the notes to read, free and instant.

Keep going

← Chemical cells and fuel cellsFactors affecting rate, collision theory and catalysts →Take a Chemistry test