From models to materials

Chemistry · Structure 2: Models of bonding and structure. The idea in plain words, the rules to remember, the mistake to avoid and a worked example, written and checked by Mega Lecture.

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The idea

Ionic, covalent and metallic bonding are not separate boxes. They are the corners of a bonding triangle, and most substances lie somewhere between them. The position of a substance is found from two numbers: the difference in electronegativity (Δχ) of its elements and their average electronegativity. From the position you can predict properties such as melting point, conductivity and solubility.

An alloy is a mixture of a metal with other metals or non-metals. Atoms of a different size disturb the regular layers, so the layers slide less easily and the alloy is harder and stronger than the pure metal.

A polymer is a very large molecule made by joining many small molecules called monomers.

Rules to remember

Common mistake

Drawing the repeating unit with the C=C double bond still in it, or putting a side group such as CH3 into the chain. Only the two double-bonded carbons form the backbone.

Worked example

Magnesium has electronegativity 1.3 and oxygen 3.4. Where does magnesium oxide lie on the bonding triangle, and what does this predict?

  1. Δχ = 3.4 − 1.3 = 2.1.
  2. Average χ = (3.4 + 1.3) ÷ 2 = 4.7 ÷ 2 = 2.35.
  3. A difference as large as 2.1 puts MgO in the ionic region.

Answer: Ionic region: high melting point, conducts electricity when molten but not when solid

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