N2O4(g) ⇌ 2NO2(g), ΔH = +57 kJ mol−1. N2O4 is colourless and NO2 is brown. What happens to the colour and to Kc when the mixture is heated at constant volume?
- ΔH is positive, so the forward reaction is endothermic.
- Raising the temperature shifts the position in the endothermic direction, which is to the right.
- More brown NO2 forms and [N2O4] falls.
- Kc = [NO2]2 ÷ [N2O4], so its value gets larger.
Answer: The mixture turns a darker brown and Kc increases.