How far? The extent of chemical change

Chemistry · Reactivity 2: How much, how fast and how far?. The idea in plain words, the rules to remember, the mistake to avoid and a worked example, written and checked by Mega Lecture.

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The idea

Many reactions are reversible. In a closed system they reach dynamic equilibrium: the forward and reverse reactions are still going on, at equal rates, so the concentrations stay constant. They are constant, not necessarily equal.

The equilibrium constant, Kc, puts product concentrations over reactant concentrations. A large K means mostly products; a very small K means mostly reactants. Only a change in temperature changes K.

Le Châtelier's principle: when a system at equilibrium is disturbed, the position shifts in the direction that reduces the change. Use it for changes in concentration, pressure and temperature. A catalyst speeds up both directions equally, so it does not move the position.

Rules to remember

Common mistake

Students say K changes when concentration or pressure changes. The position of equilibrium shifts, but the value of K stays the same unless the temperature changes.

Worked example

N2O4(g) ⇌ 2NO2(g), ΔH = +57 kJ mol−1. N2O4 is colourless and NO2 is brown. What happens to the colour and to Kc when the mixture is heated at constant volume?

  1. ΔH is positive, so the forward reaction is endothermic.
  2. Raising the temperature shifts the position in the endothermic direction, which is to the right.
  3. More brown NO2 forms and [N2O4] falls.
  4. Kc = [NO2]2 ÷ [N2O4], so its value gets larger.

Answer: The mixture turns a darker brown and Kc increases.

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