A discrete random variable X takes separate values, each with its own probability. A table of the values and their probabilities is the probability distribution, and the probabilities must add up to 1.
The expected value E(X) is the long-run average of X: multiply each value by its probability and add. A game is fair when the expected gain is zero, so the expected winnings equal the cost of playing.
The binomial distribution B(n, p) counts the number of successes in n trials. It fits only when the number of trials is fixed, each trial has two outcomes, the trials are independent, and the probability of success p stays the same.