How many unpaired electrons are there in a ground-state iron atom (Z = 26)?
- Fill in Aufbau order: 1s2 2s2 2p6 3s2 3p6 4s2 3d6 (2 + 2 + 6 + 2 + 6 + 2 + 6 = 26).
- All subshells except 3d are full, so all their electrons are paired.
- The 3d subshell has 5 orbitals. By Hund's rule the first 5 electrons go in singly and the 6th pairs with one of them.
- That leaves 1 pair and 4 single electrons.
Answer: 4 unpaired electrons