Polymers

MDCAT Chemistry · Chemistry · Macromolecules. The idea in plain words, the rules to remember, the mistake to avoid and a worked example, written and checked by Mega Lecture.

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The idea

A polymer is a very large molecule built from many small molecules called monomers. There are two ways of joining them.

In addition polymerisation, monomers with a C=C bond add to each other. The π bond opens and nothing is lost, so the polymer has the same empirical formula as the monomer.

In condensation polymerisation, each monomer has two functional groups. They join through ester or amide links, and a small molecule such as water or HCl is lost each time a link forms.

A homopolymer is made from one kind of monomer. A copolymer is made from two or more kinds of monomer in the same chain.

Rules to remember

Common mistake

Students call any polymer made from two starting chemicals an addition copolymer. Check whether a small molecule is lost: nylon-6,6 and Terylene lose water, so they are condensation polymers.

Worked example

A polyethene chain has a relative molecular mass of 56 000. How many ethene units does it contain? (H = 1, C = 12)

  1. Polyethene is an addition polymer, so the repeating unit –CH2–CH2– has the same mass as the monomer.
  2. Mr of ethene, C2H4 = 24 + 4 = 28.
  3. Number of units = 56 000 ÷ 28 = 2000.

Answer: 2000 ethene units

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