Electric potential at a point is the work done per unit positive charge in bringing a charge from infinity to that point. It is a scalar, so potentials from several charges add with their signs. A positive charge moves freely towards lower potential; an electron moves towards higher potential. Either way the charge gains kinetic energy equal to charge × potential difference.
The electron-volt is the energy gained by one electron moving through 1 V.
A capacitor stores charge and energy. Capacitors in parallel have the same potential difference and their capacitances add. Capacitors in series carry the same charge and combine by reciprocals, the opposite of resistors.