Atoms, molecules, ions and isotopes

Chemistry · Basic concepts. The idea in plain words, the rules to remember, the mistake to avoid and a worked example, written and checked by Mega Lecture.

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The idea

An atom is the smallest particle of an element that can take part in a chemical reaction. A molecule is the smallest particle of a substance that can exist on its own. An ion is an atom or group of atoms that carries a charge.

Atoms are far too light to weigh one by one, so their masses are compared with carbon-12. This gives the relative atomic mass, measured in amu.

Most elements are mixtures of isotopes: atoms with the same number of protons but different numbers of neutrons. A mass spectrometer separates the isotopes and shows how much of each is present. From this we calculate the average, which is the relative atomic mass of the element.

Rules to remember

Common mistake

Students take a simple average of the isotope masses. The average must be weighted: multiply each mass by its percentage abundance before adding.

Worked example

Chlorine has two isotopes: chlorine-35 (75% abundance) and chlorine-37 (25% abundance). What is the relative atomic mass of chlorine?

  1. Multiply each mass by its abundance: 35 × 75 = 2625 and 37 × 25 = 925.
  2. Add them: 2625 + 925 = 3550.
  3. Divide by 100: 3550 ÷ 100 = 35.5.

Answer: 35.5 amu. It is nearer to 35 because chlorine-35 is the more abundant isotope.

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