Concentration units

Chemistry · Solutions. The idea in plain words, the rules to remember, the mistake to avoid and a worked example, written and checked by Mega Lecture.

Test this topic freeAll Chemistry topics

The idea

The concentration of a solution tells you how much solute is dissolved in a given amount of solvent or solution. The same solution can be described in several units, so always read which one the question is using.

Percentage units compare the solute with 100 parts of solution. Molarity counts moles of solute in 1 dm3 of solution. Molality counts moles of solute in 1 kg of solvent. Mole fraction compares moles with total moles.

Volume changes with temperature but mass does not. So molarity changes slightly when a solution is warmed, while molality and mole fraction stay the same. When a solution is diluted, the moles of solute do not change.

Rules to remember

Common mistake

Molarity uses the volume of the whole solution, but molality uses the mass of the solvent only. Do not divide by the mass of the solution when finding molality, and change cm3 to dm3 and g to kg first.

Worked example

What volume of 12 mol dm−3 hydrochloric acid is needed to make 600 cm3 of 0.50 mol dm−3 acid?

  1. Moles of HCl do not change on dilution, so M1V1 = M2V2.
  2. 12 × V1 = 0.50 × 600 = 300
  3. V1 = 300 ÷ 12 = 25 cm3

Answer: 25 cm3 of the concentrated acid, made up to 600 cm3 with water.

Ask about this

Type what you are stuck on. The helper finds the explanation, worked examples and the notes to read, free and instant.

Read the full notes

Keep going

← Ionic equilibria: pH, buffers and solubility productRaoult's law, ideal and non-ideal solutions →Take a Chemistry test