Periodic trends, ionic and covalent bonds

Chemistry · Chemical bonding. The idea in plain words, the rules to remember, the mistake to avoid and a worked example, written and checked by Mega Lecture.

Test this topic freeAll Chemistry topics

The idea

Atoms bond to reach a more stable, lower-energy arrangement, usually the electronic configuration of a noble gas. How an atom bonds depends on how strongly it holds its own electrons and attracts others. Four properties measure this: atomic radius, ionisation energy, electron affinity and electronegativity.

An ionic bond forms when a metal atom transfers electrons to a non-metal atom and the oppositely charged ions attract each other. A covalent bond forms when two atoms share electrons: one, two or three shared pairs give single, double or triple bonds.

In a coordinate covalent bond both shared electrons come from one atom, the donor. The other atom, the acceptor, has room for the pair.

Rules to remember

Common mistake

Students say atoms get bigger across a period because they have more electrons. The extra electrons go into the same shell while the nuclear charge increases, so the atoms get smaller and ionisation energy rises.

Worked example

Electronegativities: H = 2.1, Na = 0.9, Cl = 3.0. Predict the type of bond in HCl and in NaCl.

  1. HCl: difference = 3.0 − 2.1 = 0.9. This is more than 0 but less than 1.7.
  2. NaCl: difference = 3.0 − 0.9 = 2.1. This is more than 1.7.

Answer: The bond in HCl is polar covalent; the bond in NaCl is mainly ionic.

Ask about this

Type what you are stuck on. The helper finds the explanation, worked examples and the notes to read, free and instant.

Read the full notes

Keep going

← Quantum numbers, orbitals and electronic configurationVSEPR theory, valence bond theory and hybridisation →Take a Chemistry test