Yield and atom economy

Chemistry · Quantitative chemistry. The idea in plain words, the rules to remember, the mistake to avoid and a worked example, written and checked by Mega Lecture.

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The idea

The theoretical yield is the maximum mass of product that the balanced equation says can be made. The mass actually obtained is usually less. Percentage yield compares the two.

The yield is below 100% because the reaction may be reversible and not go to completion, some product is lost when it is separated from the mixture, or some reactants react in other ways.

Atom economy is different. It is worked out from the equation only and shows what percentage of the mass of the reactants ends up in the product you want. A high atom economy means less waste, so the process is more sustainable and usually cheaper.

Rules to remember

Common mistake

Students mix up the two ideas. Percentage yield uses the mass measured in the experiment; atom economy uses only the Mr values in the balanced equation.

Worked example

CaCO3 → CaO + CO2. Heating 200 g of calcium carbonate gives 84 g of calcium oxide. What is the percentage yield? (Ar: Ca 40, C 12, O 16)

  1. Mr of CaCO3 = 40 + 12 + 48 = 100, so 200 g is 200 ÷ 100 = 2.0 mol.
  2. Ratio CaCO3 : CaO is 1 : 1, so 2.0 mol of CaO can form.
  3. Theoretical mass of CaO = 2.0 × 56 = 112 g.
  4. Percentage yield = (84 ÷ 112) × 100 = 75%.

Answer: Percentage yield = 75%

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