Crystalline solids

Chemistry · Liquids and solids. The idea in plain words, the rules to remember, the mistake to avoid and a worked example, written and checked by Mega Lecture.

Test this topic freeAll Chemistry topics

The idea

In a crystalline solid the particles are arranged in a regular, repeating three-dimensional pattern. This gives a sharp melting point, flat faces at fixed angles, cleavage along definite planes and anisotropy (some properties differ with direction). An amorphous solid, such as glass, has no regular long-range order and softens over a range of temperature.

The pattern of points in space is the crystal lattice. Its smallest repeating part is the unit cell, described by three edge lengths (a, b, c) and three angles (α, β, γ). These give seven crystal systems.

Crystals are also classed by their particles and forces: ionic, covalent, molecular and metallic. The forces decide hardness, melting point and conductivity.

Rules to remember

Common mistake

Students mix up isomorphism and polymorphism. Isomorphism is many substances sharing one crystal form; polymorphism is one substance having many crystal forms (called allotropy when the substance is an element).

Worked example

Solid X is extremely hard, melts above 2500 °C and does not conduct electricity as a solid or when molten. Which type of crystalline solid is X?

  1. No conduction when molten means there are no free ions, so X is not ionic.
  2. No conduction as a solid means there are no free electrons, so X is not metallic.
  3. Great hardness and a very high melting point mean strong bonds run through the whole crystal, so X is not molecular.

Answer: X is a covalent (network) solid, like diamond or silicon carbide.

Ask about this

Type what you are stuck on. The helper finds the explanation, worked examples and the notes to read, free and instant.

Read the full notes

Keep going

← Evaporation, vapour pressure, boiling point and liquid crystalsDiscovery of subatomic particles and Rutherford's model →Take a Chemistry test