How many isomers have the molecular formula C2H2Cl2, counting cis and trans forms separately?
- Both Cl atoms on one carbon: CH2=CCl2 (1,1-dichloroethene). Each carbon has two identical atoms, so there is no cis-trans pair: 1 isomer.
- One Cl on each carbon: CHCl=CHCl (1,2-dichloroethene). Each carbon has two different atoms, H and Cl, so cis and trans forms exist: 2 isomers.
- Total = 1 + 2 = 3.
Answer: Three isomers: 1,1-dichloroethene, cis-1,2-dichloroethene and trans-1,2-dichloroethene.